Stille couplings catalytic in tin: a "Sn-F" approach.
نویسندگان
چکیده
A new tin recycling method for Stille couplings catalytic in tin is reported. PMHS made hypercoordinate by KF((aq)) allows Me(3)SnH to be efficiently recycled during a Pd(0)-catalyzed hydrostannation/Stille cascade. Relative to previously disclosed protocols, reaction times are shorter and because this process is believed to proceed through a Me(3)SnF intermediate the hazards and problems associated with trimethyltins are also diminished.[reaction: see text]
منابع مشابه
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ورودعنوان ژورنال:
- Organic letters
دوره 3 26 شماره
صفحات -
تاریخ انتشار 2001